Thermal decomposition of bulk cobalt nitrate hydrate proceeds in several not. Jul 01, 2005 thermal decomposition tg of cobaltiinitrate hexahydrate in n 2 atmosphere showing the influence of sample loading and possible side reaction with leaving water encirclement. It is a hydrate, a cobalt salt and an inorganic nitrate salt. It is often a red brownish color and a deliquescent salt that is water soluble. Cobaltii chloride is an inorganic compound of cobalt and chlorine, with the formula cocl 2.
Catalyst handbook, 2nd ed wolfe publishing ltd london, england, 1989. You can view more details on each measurement unit. Webelements periodic table cobalt cobalt nitrate hexahydrate. Cobalt nitrate is the inorganic compound with the formula cono32. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered. A hydrate that is the hexahydrate form of cobalt dinitrate. The most common form is the hexahydrate co no 3 2 6h 2 o, which is a redbrown deliquescent salt that is soluble in water and other polar solvents. Rapid heating of cobaltiinitrate hexahydrate causes melting formation of a hydrate melt and therefore side reactions in the hydrate melt by. It is created by the interaction of cobalt oxide, hydroxide or. Based on the thermal decomposition studies of cobalt ii nitrate hexahydrate 43, it is possible to propose the scheme of the crystal decomposition.
It loses water on heating and changes to a blue colored compound. Nitric acid cobalt salt hexahydrate company identification. Convert moles cobaltii nitrate hexahydrate to grams. As well as the anhydrous compound co no 3 2, several hydrates of cobalt ii nitrate exist. Nov 28, 2014 the final product of bulk cobalt nitrate decomposition is co 3 o 4, which was confirmed by xrd analysis not shown here and stays in agreement with results presented in the literature 22, 24. Catalytic decomposition of sodium chlorate sciencedirect. Add to the flask suspended in water cobalt compound and then add small parts of hot ammonium nitrate solution with heating and stirring. Physical cobaltii sulfate is a red anhydrous, monohydrate or pink hexa, heptahydrate crystalline solid, soluble in water, with the hydrated form more soluble in. The hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. Not combustible but enhances combustion of other substances. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of usehandling. Cobalt nitrate is the inorganic compound with the formula co no 3 2. Hexahydrate cobalt nitrate was supplied by vetec, while pamino benzoic acid was supplied by sigmaaldrich.
Calculate how many grams you need to prepare 50 ml of 0. Thermogravimetric analysis tga studies of cobalt nitrate hexahydrate, cupric nitrate trihydrate, ferric. Hereafter, the catalyst prepared from cobalt carbonate will be referred to as catalyst i. Cobalt nitrate hexahydrate is generally immediately available in most volumes. How many ml of the solution from question 1 do you need to prepare 50 ml of a 0. Add to the flask with calcium or lead nitrate solution small parts of cobalt salt. Cobalt oxide catalysts were prepared from the nitrate by thermal decomposition of cobalt nitrate hexahydrate at 691 for 20 hr. This information was last updated on september 8, 2003. Thermal decomposition of bulk cobalt nitrate hydrate proceeds in several not well separated stages fig. Temperature programme reduction tpr studies of cobalt phases in. The nitrate anion is a univalent 1 charge polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms formula.
Thermal studies of nickel, cobalt, iron and copper oxides and. Decomposition of cobalt nitrate supported on al 2 o 3 leads to coal 2 o 4 spinel as the final product at the temperature 210 c fig. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the molecular and structural formulas. Physical cobalt ii sulfate is a red anhydrous, monohydrate or pink hexa, heptahydrate crystalline solid, soluble in water, with the hydrated form more soluble in. Cobalt ii nitrate hexahydrate substance information echa. Rapid heating of cobaltiinitrate hexahydrate causes melting formation of a. Record the exact mass of the cobaltii nitrate hexa hydrate in the data table and transfer it to a 100 ml beaker.
The final product of bulk cobalt nitrate decomposition is co 3 o 4, which was confirmed by xrd analysis not shown here and stays in agreement with results presented in the literature 22, 24. Cobalt ii nitrate hexahydrate, 99% catalog numbers. It is a sky blue crystalline solid the compound forms several hydrates cocl 2 n h 2 o, for n 1, 2, 6, and 9. These products are not to be used as human or animal therapeutics, cosmetics, agricultural or pesticidal products, food additives, or as household chemicals. The chart below shows the calculated isotope pattern for the formula cono 3 3 with the most intense ion set to 100%. Cobaltii nitrate cobaltous nitrate cobaltous nitrate hexahydrate keep people away. We have tried to make it as accurate and useful as possible, but can take no responsibility for its use, misuse, or accuracy. Structure, properties, spectra, suppliers and links for.
Request pdf thermal decomposition of cobalt nitrato compounds. What is the formula of cobalt ii chloride hexahydrate. You have selected the maximum number of product attributes 3 to compare. The decomposition of metal nitrates in air has been systematically studied. Cobaltii nitrate react with ammonium hydroxide to produce cobaltii hydroxide and ammonium nitrate. Thermal decomposition of d metal nitrates supported on. Search results for cobaltii nitrate hexahydrate at sigmaaldrich. Sep 20, 2009 cobaltii chloride hexahydrate has a pink color. Kinetics of the thermal decomposition of anhydrous cobalt. As it is in detail described in the literature, the. Cobalt nitrate cco cautionary response information common synonyms solid red odorless sinks and mixes with water. Simple method to synthesize functionalized carbon nanotubes. More about the price and coa of cobaltii nitrate hexahydrate,please visit our website, and contact us. Thermal decomposition of metal nitrates in air and hydrogen.
One reagent lane fair lawn, nj 07410 for information in north america, call. Cobalt nitrate, hexahydrate, crystal, reagent, acs is an inorganic cobalt salt of nitric acid. The oxidation number of cobalt in cobalt nitrate hexahydrate is 2. Preparation of nanoco3o4 by direct thermal decomposition of. Mixtures of metalnonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates. Cobalt nitrate is a highly water soluble crystalline cobalt source for uses compatible with nitrates and lower acidic ph. John dallas donaldson, detmar beyersmann, cobalt and cobalt compounds in ullmanns. Cobaltii nitrate hexahydrate, thermal decomposition, nanoco3o4, characterization, filterpaperderived carbon electrode, electrochemical water. The most common form is the hexahydrate cono326h2o, which is a. Thermal decomposition of d metal nitrates supported on alumina. Honeywell fluka cobaltii nitrate hexahydrate, honeywell. Gives off irritating or toxic fumes or gases in a fire. Cobaltii nitrate hexahydrate h12con2o12 chemspider. Webelements periodic table cobalt cobalt trinitrate.
All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. Cobaltous nitrate hexahydrate, cobaltous nitrate, nitric acid, cobalt ii salt cas number 10026229. Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. A chemical reaction of cobaltii nitrate with sodium. Claims of the formation of tri and tetrahydrates have not been confirmed. First aid measures always seek professional medical attention after first aid measures are provided.
The very slow thermal decomposition of 1, presented in fig. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. In figure 3 are identified cobalt oxide residues at the end of the test tgadsc, and the percentages of weight loss in water, nitrogen oxides, to be corroborated from the calculations in hsc 5. The sample was ground lightly mid way in the heating cycle and finally stored in a desiccator over anhydrous calcium sul fate. Cobalt ii nitrate hexahydrate revision date 19jan2018 hazard class 5. Thermal decomposition tg of cobaltiinitrate hexahydrate in n 2 atmosphere showing the influence of sample loading and possible side reaction with leaving water encirclement. Search results for cobalt nitrate hexahydrate at sigmaaldrich. Use the product attributes below to configure the comparison table. Cobaltii nitrate hexahydrate, 99%, pure, acros organics. Shut off ignition sources and call fire department. We assume you are converting between moles cobaltii nitrate hexahydrate and gram. The hazard classification and labelling section shows the hazards of a substance based on the standardised system of statements and pictograms established under the clp classification labelling and packaging regulation. Cobalt nitrate is the inorganic cobaltii salt of nitric acid, often with various amounts of water. Cobalt ii nitrate cobaltous nitrate cobaltous nitrate hexahydrate keep people away.
Cobalt nitrate is generally immediately available in most volumes. Also record the appearance of the crystals in the observations section below the data. The base metal hydrate, cano324h2o, showed two successive. Standard thermodynamic properties of chemical substances continued molecular. Abstract the thermal decomposition of cobalt, nickel, manganese, zinc, and. The clp regulation makes sure that the hazards presented by chemicals are clearly communicated to. The crystal structure of cobalt nitrate dihydrate, cono32 2 h2o in. Cobalt nitrate cono 3 2 6h 2 o is a red crystalline compound with a melting point of 56 c. Product and company identification cobalt nitrate, 6hydrate synonymsgeneral names. Investigated as a tumorigen and a reproductive effector. This material contains cobaltii nitrate anhydrous listed as cobalt compounds.
Based on the thermal decomposition studies of cobaltii nitrate hexahydrate 43, it is possible to propose the scheme of the crystal decomposition. Used as a battery additive, in the manufacture of cobalt pigments and invisible inks, for. Cobalt nitrate hexahydrate cas no 10141056 anhydrous. Cobalt ii nitrate hexahydrate substance information. Thermodynamic properties of substances the solubility of. To elucidate the unusual quasiisothermal driving modus of the investigation method examplarily the time dependence on the mass loss and on the temperature, respectively, is shown. Cobaltii nitrate hexahydrate for sale,price,buy cobalt.
Material safety data sheet cobaltii nitrate hexahydrate. Safety data sheet according to 29cfr19101200 and ghs rev. The substance identity section is calculated from substance identification information from all echa databases. Products sold by phytotechnology laboratories are intended for plant research and laboratory use only. It has been shown the ability of the sample controlled reaction temperature scrt method for both discriminate the kinetic law and calculate the activation energy of the reaction. This thermal decomposition is best described by a johnsonmehlavrami kinetic model with n 2 with an activation energy of nuclei growth which fall in the range 5259 kj mol.
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